Does your boiler have a feed and expansion tank in the loft ? if it has is it higher than the radiator and half full of water ? (it should be,obviously.
If you have a f&e tank and it is higher than the rad turn off the pump and try to bleed the rad, some times the air vent can be blocked with dirt.
If the f&e tank is at the same height as the rad try to bleed the rad with the pump running.
With a f&e tank the cold feed to the system could be blocked.
If you have a sealed system with no f&e tank check the pressure is high enough It takes roughly 1 Bar of pressure to to fill rads 10m above pressure gauge on the system.