Nowhere enough information to go on.
If it's anything like a Honeywell Y-Plan, it could be anything like the motorised valve or the room thermostat.
Basic bimetallic thermostats (hear them click), are pretty robust, but do fail.
Cheap to replace.
The motorised valve controls the boiler and the thermostats, room and hot water cylinder, control the motorised valve.
In any case, you'd be best getting it checked.
If it went wrong once, it'll do it again.